'Walther Ludwig Julius Kossel' (
January 4,
1888 in
Berlin, Germany –
22 May,
1956 in
Tübingen, Germany) was a German
physicist known for his theory of the
chemical bond (
ionic bond/
octet rule),
Sommerfeld-Kossel displacement law of atomic spectra, the Kossel-Stranski model for crystal growth, and the Kossel effect. Walther was the son of
Albrecht Kossel who won the
Nobel Prize in Physiology or Medicine in
1910.
Career
Kossel began studies at the
University of Heidelberg in
1906, but was at the
University of Berlin during
1907 and
1908. In
1910, he became assistant to
Philipp Lenard, who was also his thesis advisor. Kossel was awarded his Ph.D. in
1910, and he stayed on as assistant to Leonard until
1913.
[1]
In 1913, the year in which
Niels Bohr introduced the
Bohr model of the atom, Kossel went to the
University of Munich as assistant to
Arnold Sommerfeld,
[2] under whom he did his
Habilitation. Under Sommerfeld, Munich was a theoretical center for the developing
atomic theory, especially from the interpretation of
atomic spectra. In
1916, Kossel put forth his theory of the
ionic chemical bond (
octet rule), also independently advanced in the same year by
Gilbert N. Lewis.
[3] In papers published in
1914,
1916, and
1920, Kossel was the first to explain the theory of absorption limits in
x-ray spectra.
[4] The edge appears at a critical frequency where absorption of the radiation largely begins with the resultant ejection of
photoelectrons. In
1919, Kossel and Sommerfeld explained the similarity of the
atomic spectra of neutral atoms, of
atomic number Z, and singly ionized atoms, of atomic number Z + 1, which became known as the
Sommerfeld-Kossel displacement law.
[5] In
1920, Kossel explained another phenomenon of x-ray spectra. Under high resolution spectroscopy, the absorption edge has structure.
[6] He attributed this to absorption of radiation by electrons which are not ejected from matter as photoelectrons, but are “kicked up” to higher, unoccupied, bound electron energy levels. In early years, this was known as “
Kossel structure.”
In
1921, Kossel took an appointment as ordinarius professor of theoretical physics at the
University of Kiel.
[7] In
1928, he put forth his kinetic theory of crystal growth, which became known as the Kossel-Stranski model – Iwan N. Stranki
[8] independently proposed the same model.
[9]
In
1932, Kossel took the appointment as ordinarius professor of theoretical physics at the
Technische Hochschule at Danzig.
[10] During his tenure there in 1934, he discovered x-ray lattice interference of spherical waves in crystals during the bombardment of single-crystal copper with a high-energy electron beam.
[11]
In
1944, he was awarded the
Max-Planck medal by the
Deutsche Physikalische Gesellschaft.
In
1945, Kossel became professor of theoretical physics and director of the Physics Institute at the
University of Tübingen, where he was granted emeritus status in
1953.
[12]
Kossel died in Tübingen and is buried, as is his father, Albercht, in the Wald Friedhof, Heidelberg.
[13]
Selected bibliography
★ Walther Kossel ''Bemerkung zur Absorption homogener Röntgenstrahlen'', ''Verh. D. Deutsch. Phys Ges'' (2) '16' 898-909 (1914). Received 27 September 1914, published in issue No. 20 of 30 October 1914. As cited in Mehra, Volume 1, Part 2, 2001, p. 795.
★ Walther Kossel ''Bemerkung zur Absorption homogener Röntgenstrahlen. II'', ''Verh. D. Deutsch. Phys Ges'' (2) '16' 953-963 (1914). Received 23 October 1914, published in issue No. 22 of 30 November 1914. As cited in Mehra, Volume 5, Part 2, 2001, p. 919.
★ Walther Kossel ''Bemerkung zum Seriencharakter der Röntgenstrahlen'', ''Verh. D. Deutsch. Phys Ges'' (2) '18' 339-359 (1916). Received 31 August 1916, published in issue No. 15-18 of 30 September 1916. As cited in Mehra, Volume 5, Part 2, 2001, p. 919.
References
★ Borisenko, Victor E. and Stefano Ossicini ''What is What in the Nanoworld: A Handbook on Nanoscience and Nanotechnology''(Wiley-VCH, 2004) ISBN 3-527-40493-7
★ Cao, Gouzhong ''Nanostructures and Nanomaterials: Synthesis, Properties, and Applications'' (Imperial College Press, 2004) ISBN 1-86094-415-9
★
Gerhard Herzberg translated from German with the help of the author by J. W. T. Spinks ''Atomic Spectra and Atomic Structure'' (Dover, 1945)
★ Mehra, Jagdish, and Helmut Rechenberg ''The Historical Development of Quantum Theory. Volume 1 Part 2 The Quantum Theory of Planck, Einstein, Bohr and Sommerfeld 1900 – 1925: Its Foundation and the Rise of Its Difficulties.'' (Springer, 2001) ISBN 0-387-95175-X
★ Mehra, Jagdish, and Helmut Rechenberg ''The Historical Development of Quantum Theory. Volume 5 Erwin Schrödinger and the Rise of Wave Mechanics. Part 2 Schrödinger in Vienna and Zurich 1887-1925.'' (Springer, 2001) ISBN 0-387-95180-6
★ Pauling, Linus ''The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry'' (Cornell, 1960)
★ White, Harvey Elliott ''Introduction to Atomic Spectra'' (McGraw-Hill, 1934)
Notes
1. American Philosophical Society Author Catalog: Kossel and American Philosophical Society: Sommerfeld Biography
2. American Philosophical Society: Sommerfeld Biography
3. University College Cork, University City Tübingen, and (Pauling, 1960, p. 5).
4. White, 1934, p. 307
5. White, 1934, p. 249
6. White, 1934, p. 329
7. American Philosophical Society Author Catalog: Kossel
8.
Iwan N. Stranksi. The Institute for Physical and Theoretical Chemistry, at the Technical University Berlin, was named in his honor. See: Stranski-Laboratorium für Physikalische und Theoretische Chemie
9. Cao, 2004, p. 116 and Borisenko, 2004, p. 154.
10. American Philosophical Society Author Catalog: Kossel
11. Synchrotron Radiation in Natural Science and Crystal Research Technology
12. 50 Years of X-ray Diffraction: Germany,
University of Tübingen, and German Wikipedia: Kossel
13.
50 Years of X-ray Diffraction: Germany and University City Tübingen