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 A temperature-versus-entropy diagram for steam |
 A Mollier enthalpy-versus-entropy diagram for steam |
In
physical chemistry, and in
engineering, 'steam' refers to vaporized water. It is a pure, completely invisible
gas (for
mist see below). Pure steam (unmixed with air, but in equilibrium with water-liquid) at standard atmospheric pressure, and occupies about 1,600 times the volume of liquid water In the atmosphere, the
partial pressure of water is much lower than 1 atm, therefore gaseous water can exist at temperatures much lower than 100 C (see
water vapor and
humidity).
''In common speech,'' 'steam' most often refers to the white
mist that condenses above boiling water as the hot vapor ("steam" in the first sense) mixes with the cooler air. This mist is made of tiny droplets of liquid water, not gaseous water, so it is no longer technically steam. In the spout of a steaming kettle, the spot where there is no condensed water vapor, where there appears to be nothing there, is steam.
Uses
A
steam engine uses the expansion of steam to drive a
piston or
turbine to perform
mechanical work. In other industrial applications steam is used as a repository of energy, which is introduced and extracted by heat transfer, usually through pipes. Steam is a capacious reservoir for energy because of water's high
heat of vaporization. The ability to return condensed steam as water-liquid to the boiler at high pressure with relatively little expenditure of pumping power is also important. Engineers use an idealised thermodynamic cycle, the
Rankine cycle, to model the behaviour of steam engines.
In the U.S., more than 86% of electric power is produced using steam as the
working fluid, nearly all by steam turbines. Condensation of steam to water often occurs at the low-pressure end of a steam turbine, since this maximises the energy efficiency, but such wet-steam conditions have to be limited to avoid excessive turbine blade erosion.
When liquid water comes in contact with a very hot substance (such as
lava, or molten metal) it can flash into steam very quickly; this is called a '
steam explosion'. Such an explosion was probably responsible for much of the damage in the
Chernobyl accident and for many so-called 'foundry accidents'.
Steam's capacity to transfer heat is also used in the home: for cooking vegetables, steam cleaning of fabric and carpets, and heating buildings. In each case, water is heated in a boiler, and the steam carries the energy to a target object. "
Steam showers" are actually low-temperature mist-generators, and do not actually use steam.
In electric generation, steam is typically condensed at the end of its expansion cycle, and returned to the boiler for re-use. However in
cogeneration, steam is piped into buildings to provide heat energy after its use in the electric generation cycle. The world's biggest steam generation system is
Con Edison in
New York City which pumps steam into 100,000 buildings in
Manhattan from seven cogeneration plants.
[1]
References
1. http://www.gothamgazette.com/article/issueoftheweek/20031110/200/674
See also
★
Geyser – ''geothermally-generated steam''
★
Steam engine
★
Steam locomotive
★
Live steam
★
Steam shower
★
Steam house
★
Nuclear power – ''uses steam to generate electricity''
★
Psychrometrics – ''moist air/vapour mixtures, humidity and air conditioning''
★
IAPWS – ''an association that maintains international-standard correlations for the
thermodynamic properties of steam, including IAPWS-IF97 (for use in industrial simulation and modelling) and IAPWS-95 (a general purpose and scientific correlation).''
External links
★
Steam Tables & Charts by National Institute of Standards and Technology, NIST
★
What Is Steam? ''(general article about the properties of water/steam)''
★
Steam Tracing
★
Online steam properties calculator (Spirax Sarco)