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| General | |
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| Systematic name | trisodium 2-hydroxypropane-1,2,3-tricarboxylate |
| Other names | citrosodine; trisodium citrate; citric acid, trisodium salt |
| Molecular formula | Na3C6H5O7 |
| SMILES | [Na+].[Na+].[Na+]. O=C([O-])CC(O)(CC(=O)[O-])C([O-])=O |
| Molar mass | 258.07 g/mol |
| Appearance | White crystalline powder |
| CAS number | [68-04-2] (anhydrous); [6132-04-3] (dihydrate) |
| Properties |
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| Density and phase | ~ 1.7 g/cm³ solid |
| Solubility in water | 72 g/100 ml |
| Melting point | 150 °C |
| Boiling point | Decomposes |
| Acidity (p''K''a) | ? |
| Basicity (p''K''b) | ? |
| Structure |
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| Crystal structure | ? |
| Dipole moment | ? D |
| Hazards |
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| MSDS | External MSDS |
| Main hazards | Irritant |
| NFPA 704 | |
| Flash point | ?°C |
| R/S statement | R: ? S: ? |
| RTECS number | ? |
| Supplementary data page |
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Structure and properties | ''n'', εr, etc. |
Thermodynamic data | Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Related compounds |
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| Related compounds | calcium citrate, citric acid |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
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'Sodium citrate' is the
sodium salt of
citric acid with the chemical formula of Na
3C
6H
5O
7. Sodium citrate possesses a saline, mildly tart, flavor. For this reason, citrates of certain Alkaline and Alkaline Earth metals (e.g. sodium and calcium citrates) are commonly known as ''sour salt'' (occasionally citric acid is erroneously termed ''sour salt''). Sodium citrate is chiefly used as a
food additive, usually for
flavor or as a
preservative. Sodium citrate is employed as a flavoring agent in certain varieties of
club soda.
Sodium citrate is common as an ingredient in lemon-lime and citrus
soft drinks such as
Ting, contributing to their tart tastes, and can also be found in such energy drinks as
Rockstar and
Red Bull.
In
1914, the
Belgian doctor
Albert Hustin and the
Argentine physician and researcher
Luis Agote successfully used sodium citrate as an
anticoagulant in
blood transfusions. It continues to be used today in blood collection tubes and for the preservation of
blood in
blood banks. The citrate ion
chelates calcium ions in the blood, disrupting the blood clotting mechanism.
As a
conjugate base of a weak acid, citrate can perform as a
buffering agent, resisting changes in
pH. Sodium citrate is used to control
acidity in some substances, such as
gelatin desserts. It can be found in the mini milk containers used with coffee machines. The compound is the product of antacids such as Alka-Seltzer when they are dissolved in water.
Research from the British Journal of Sports Medicine (2003) showed that use of sodium citrate (approx. 37 grams) improved running performance over 5 km by 30 seconds.
[1]
Sodium citrate is used to relieve discomfort in urinary tract infections such as
cystitis, to reduce the acidosis seen in distal
renal tubular acidosis, and can also be used as an osmotic
laxative.
References
1. Oopik, V et al 2003; 37: 485-489