(Redirected from Sinter)
'Sintering' is a method for making objects from
powder, by heating the material (below its
melting point) until its particles
adhere to each other. Sintering is traditionally used for manufacturing
ceramic objects, and has also found uses in such fields as
powder metallurgy.
The word "sinter" comes from the
Middle High German ''Sinter'', a
cognate of English "
cinder".
Sintered
bronze in particular is frequently used as a material for
bearings, since its porosity allows lubricants to flow through it. In the case of materials with high melting points such as
Teflon and
tungsten, sintering is used when there is no alternative manufacturing technique. In these cases very low porosity is desirable and can often be achieved.
Sintered Bronze and Stainless steel are used as filter materials in applications requiring high temperature resistance and at the same time the ability to regenerate the filter element. For example, sintered stainless steel elements are used for filtration of steam in food and pharmaceutical applications.
In most cases the density of a collection of grains increases as material flows into voids, causing a decrease in overall volume. Mass movements that occur during sintering consist of the reduction of total porosity by repacking, followed by material transport due to
evaporation and
condensation from
diffusion. In the final stages, metal atoms move along crystal boundaries to the walls of internal
pores, redistributing mass from the internal bulk of the object and smoothing pore walls.
Surface tension is the driving force for this movement.
Metallurgists can sinter most, if not all, metals. This applies especially to pure metals produced in vacuum which suffer no surface contamination. Many nonmetallic substances also sinter, such as
glass,
alumina,
zirconia,
silica,
magnesia,
lime,
ice,
beryllium oxide,
ferric oxide, and various
organic polymers. Sintering, with subsequent reworking, can produce a great range of material properties. Changes in density,
alloying, or heat treatments can alter the physical characteristics of various products. For instance, the
tensile strength ''E
n'' of sintered
iron powders remains insensitive to sintering time, alloying, or particle size in the original powder, but depends upon the density (''D'') of the final product according to ''E
n/E = (D/d)
3.4'', where ''E'' is
Young's modulus and ''d'' is the maximum density of iron.
Particular advantages of this powder technology include:
# the possibility of very high
purity for the starting materials and their great uniformity
# preservation of purity due to the restricted nature of subsequent
fabrication steps
# stabilization of the details of repetitive operations by control of grain size in the input stages
# absence of
stringering of segregated particles and inclusions (as often occurs in melt processes)
# no requirement for
deformation to produce directional elongation of grains
Many literary references exist on sintering dissimilar materials for solid/solid phase compounds or solid/melt mixtures in the processing stage. Any substance which melts may also become atomized using a variety of powder production techniques. When working with pure elements, one can recycle scrap remaining at the end of parts manufacturing through the powdering process for reuse.
Ceramic sintering
Sintering is part of the firing process used in the manufacture of
pottery and other ceramic objects. Some ceramic raw materials have a lower
affinity for water and a lower
plasticity index than
clay, requiring organic additives in the stages before sintering. The general procedure of creating ceramic objects via sintering of powders includes:
★ Mixing water, binder,
deflocculant, and unfired ceramic powder to form a
slurry
★
Spray-drying the slurry
★ Putting the spray dried powder into a
mold and pressing it to form a ''green body'' (an unsintered ceramic item)
★ Heating the green body at low temperature to burn off the binder
★ Sintering at a high temperature to fuse the ceramic particles together
All the characteristic temperatures associated to phases transformation, glass transitions and melting points, occurring during a sinterisation cycle of a particular ceramics formulation (i.e. tails and frits) can be easily obtained by observing the expansion-temperature curves during
optical dilatometer thermal analysis. In fact, sinterisation is associated to a remarkable shrinkage of the material due to the fact that glass phases flow, once their transition temperature is reached, and start consolidating the powdery structure and considerably reducing the porosity of the material.
There are two types of sintering: with pressure (also known as hot pressing), and without pressure. Pressureless sintering is possible with graded metal-ceramic composites, with a nanoparticle sintering aid and bulk molding technology. A variant used for 3D shapes is called
hot isostatic pressing.
See also
★
Selective laser sintering, a
rapid prototyping technology.
References
:
: