'Pyroxenite' is an
ultramafic igneous rock consisting essentially of
minerals of the
pyroxene group, such as
augite and
diopside,
hypersthene,
bronzite or
enstatite. They are classified (see diagram below) into clinopyroxenites, orthopyroxenites, and the websterites which contain both pyroxenes. Closely allied to this group are the hornblendites, consisting essentially of
hornblende and other
amphiboles.
They are essentially of
igneous origin, though some pyroxenites are included in the
metamorphic complex of the Lewisian of
Scotland. The pyroxene-rich rocks which result from the
contact metamorphism of impure
limestones are described as pyroxene
hornfelses (calc-silicate hornfelses).
Intrusive and Mantle Pyroxenites
The igneous pyroxenites are closely allied to the
gabbros and
norites, from which they differ by the absence of
feldspar, and to the
peridotites, which are distinguished from them by containing more than 40%
olivine. This connection is indicated also by their mode of occurrence, for they usually accompany masses of gabbro and peridotite and seldom are found by themselves.
They are often very coarse-grained, containing individual
crystals which may be several inches in length. The principal accessory minerals, in addition to olivine and feldspar, are
chromite and other
spinels.
garnet,
magnetite,
rutile, and
scapolite.
Pyroxenites can be formed as cumulates in
ultramafic intrusions by accumulation of pyroxene crystals at the base of the lava chamber. Here they are generally associated with gabbro and anorthite cumulate layers and are typically high up in the intrusion. They may be accompanied by
magnetite layers,
ilmenite layers, but rarely
chromite cumulates.
Pyroxenites are also found as layers within masses of peridotite. These layers most commonly have been interpreted as products of reaction between ascending magmas and peridotite of the upper mantle. The layers typically are a few centimeters to a meter or so in thickness. Pyroxenites that occur as
xenoliths in
basalt and in
kimberlite have been interpreted as fragments of such layers. Although some mantle pyroxenites contain garnet, they are not
eclogites, as clinopyroxene in them is less sodic than
omphacite and the pyroxenite compositions typically are unlike that of
basalt. It has been proposed that large volumes of pyroxenite form in the upper mantle as a result of reaction between peridotite and magma derived from partial melting of eclogite, and that such pyroxenite volumes are important sources of basalt magma (e.g., Sobolev and others, 2007).
Pyroxenite lavas
Purely pyroxene-bearing volcanic rocks are rare, restricted to
spinifex textured sills, lava tubes and thick flows in the
Archaean greenstone belts. Here, the pyroxenite lavas are created by in-situ crystallisation and accumulation of pyroxene on the floor of a lava flow, creating the distinctive spinifex texture, but also occasionally mesocumulate and orthocumulate segregations. This is in essence similar to the formation of olivine spinifex textures in
komatiite lava flows, the chemistry of the magma differing only to favor crystallisation of pyroxene.
A type locality is the Gullewa Greenstone Belt, in the Murchison region of Western Australia, and the Duketon Belt near
Laverton, where pyroxene spinifex lavas are closely associated with gold deposits.
Distribution
They frequently occur in the form of
dikes or segregations in gabbro and peridotite: in
Shetland, Cortland on the
Hudson river,
North Carolina (websterite),
Baltimore,
New Zealand, and in
Saxony.

Classification diagram for peridotite and pyroxenite, based on proportions of olivine and pyroxene. The pale green area encompasses the most common compositions of peridotite in the upper part of the Earth's mantle
The pyroxenites are often subject
serpentinization under low temperature retrograde metanorphism and
weathering. The rocks are often completely replaced by
serpentines, which sometimes preserve the original structures of the primary minerals, such as the lamination of hypersthene and the rectangular cleavage of augite. Under pressure-metamorphism hornblende is developed and various types of
amphibolite and hornblende-
schist are produced. Occasionally rocks rich in pyroxene are found as basic facies of
nepheline syenite; a good example is provided by the
melanite pyroxenites associated with the ''borolanite'' variety found in the Loch Borralan igneous complex of
Scotland.
References
Sobolev, A. V., and others, 2007, ''The amount of recycled crust in sources of mantle-derived melts'', Science 316, p. 412-417. http://www.sciencemag.org/cgi/content/abstract/316/5823/412