'Phosphor bronze' is an
alloy of
copper with 3.5 to 10% of
tin and a significant
phosphorus content of up to 1%. The phosphorus is added as deoxidizing agent during melting. These alloys are notable for their
toughness,
strength, low
coefficient of friction, and fine
grain. The phosphorus also improves the
fluidity of the molten metal and thereby improves the castability, and improves mechanical properties by cleaning up the
grain boundaries.
Further increasing of phosphorus content leads to formation of a very hard compound Cu
3P (
copper phosphide), resulting in a
brittle bronze with only special uses.
Phosphor
bronze is used for
springs and other applications where resistance to fatigue, wear and chemical corrosion is required. It is also used in acoustic
instrument strings (for
acoustic guitars,
mandolins, etc...).
This alloy is also used as the metal component of some dental bridges, And it was supposedly developed in Germany during the 2nd World War when they could no longer obtain
lignum vitae for propeller shaft bearings in their submarines. Which wood had long been used for this purpose in ships. The phosphor-bronze alloy can also be used in electrical circuits due to its low resistance and high conductivity.
External links
★
Copper and copper alloy microstructures: Phosphor bronze
★
National Pollutant Inventory - Copper and compounds fact sheet