'Phosphate minerals' are those
minerals that contain the tetrahedrally coordinated
phosphate (PO
43-)
anion along with the freely substituting
arsenate (AsO
43-) and
vanadate (VO
43-).
Chlorine (Cl
-),
fluorine (F
-), and
hydroxide (OH
-) anions also fit into the crystal structure.
The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common.
Examples include:
★
triphylite Li(Fe,Mn)PO
4
★
monazite (Ce,La,Y,Th)PO
4
★
Apatite group Ca
5(PO
4)
3(F,Cl,OH)
★
★
hydroxylapatite Ca
5(PO
4)
3OH
★
★
fluorapatite Ca
5(PO
4)
3F
★
★
chlorapatite Ca
5(PO
4)
3Cl
★
pyromorphite Pb
5(PO
4)
3Cl
★
vanadinite Pb
5(VO
4)
3Cl
★
erythrite Co
3(AsO
4)
2'·'8H
2O
★
amblygonite LiAlPO
4F
★
lazulite (Mg,Fe)Al
2(PO
4)
2(OH)
2
★
wavellite Al
3(PO
4)
2(OH)
3'·'5H
2O
★
turquoise CuAl
6(PO
4)
4(OH)
8'·'5H
2O
★
autunite Ca(UO
2)
2(PO
4)
2'·'10-12H
2O
★
carnotite K
2(UO
2)
2(VO
4)
2'·'3H
2O
★
phosphophyllite Zn
2(Fe,Mn)(PO
4)
2•4H
2O
Applications
Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials, applied with electrochemical conversion coatings.
See also
★
Parkerizing
References
★ Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York ISBN 0-471-80580-7
★
Webmineral - Strunz
★
Webmineral - Dana