An 'oxoacid' is an
acid which contains
oxygen. More specifically, it is an acid which:
#contains oxygen;
#contains at least one other
element;
#has at least one
hydrogen atom bound to oxygen; and
#forms an ion by the loss of one or more protons.
The name 'oxyacid' is sometimes used, although this is not recommended.
Generally, oxoacids are simply
polyatomic ions with a hydrogen
cation.
Under
Lavoisier's original
theory, all acids contained oxygen, which was named from the
Greek οξυς (''oxys'') (acid, sharp) and γεινομαι (''geinomai'') (engender). It was later discovered that some acids, notably
hydrochloric acid, did not contain oxygen and so a distinction was made for those that did.
Common oxoacids include:
★ Halogen oxoacids:
Hypochlorous acid ;
Chlorous acid;
Chloric acid;
Perchloric acid;
Perbromic acid;
Metaperiodic acid
★
Sulfuric acid
★
Nitric acid
★
Phosphoric acid
Common acids which are not oxoacids include:
★
Hydrochloric acid
★
Hydrofluoric acid
★
Hydrobromic acid
★
Hydroiodic acid
Although
carboxylic acids fulfill the criteria above, they are not generally considered as oxoacids.
All oxoacids have the acidic hydrogen bound to an oxygen atom, so bond strength (length) is not a factor as it is with binary nonmetal hydrides. Rather, the electronegativity of the central atom (E) and the number of O atoms determine oxoacid acidity. With the same number of oxygens around E, acid strength increases with the electronegativity of E.
Note
# This final criterion has the effect of excluding
boric acid from the strict definition, as it forms its anion by addition of hydroxide rather than loss of a proton: B(OH)
3 + H
2O [B(OH)
4]
− + H
+. However, boric acid is usually considered to be an oxoacid nonetheless.
External link
★
IUPAC definition of "oxoacid" (from the "''Gold Book''")