
The structure of the oxalate anion
An 'oxalate' (also 'ethanedioate') is a
salt or
ester of
oxalic acid. As a salt, the oxalate anion has the chemical formula C
2O
42− or (COO)
22−.
Consumption of oxalates (for example, the grazing of animals on oxalate-containing plants such as
greasewood) may result in
kidney disease or even
death due to
oxalate poisoning.
The charge on oxalate allows it to act as a
chelator of various positively charged metal ions.
Much of its other properties resemble oxalic acid.
Examples
★
sodium oxalate - Na
2C
2O
4
★
calcium oxalate - CaC
2O
4, a major component of
kidney stones
★
dimethyl oxalate - (CH
3)
2C
2O
4
★
phenyl oxalate ester - (C
6H
5)
2C
2O
4
★
Potassium ferrioxalate - [K
3[Fe(C
2O
4)
3], an iron complex with oxalate ligands
★
ammonium oxalate - (NH
4)
2C
2O
4
References