'Oleochemicals' are
chemicals derived from biological
oils or
fats. They are analogous to
petrochemicals which are chemicals derived from
petroleum. The
hydrolysis or
alcoholysis of oils or fats form the basis of the oleochemical industry.
The hydrolysis of the
triglycerides composing oils and fats produces
fatty acids and
glycerol:
:RCOOCH
2-CHOOCR-CH
2OCOR + 3 H
2O → 3 RCOOH + HOCH
2-CHOH-CH
2OH
If oils or fats are made to react with an
alcohol (R'OH) instead of with water, the process is alcoholysis (also called
transesterification) and the products are fatty acid
esters and glycerol:
:RCOOCH
2-CHOOCR-CH
2OCOR + 3 R'OH → 3 RCOOR' + HOCH
2-CHOH-CH
2OH
The fatty acid or fatty esters produced by these methods may be transformed further through additional processes:
★
Hydrogenation to convert
unsaturated fatty acids into
saturated fatty acids.
★
Reduction to convert the acids or esters into
fatty alcohols