'Nepheline', also called 'nephelite' (from
Greek: ''nephos'', "cloud"), is a
feldspathoid: a silica-undersaturated aluminosilicate,
Na3KAl4Si4O16, that occurs in
intrusive and
volcanic rocks with low silica, and in their associated
pegmatites. It is very occasionally found in
mica schist and
gneiss.
Nepheline crystals are rare and belong to the hexagonal system, usually having the form of a short, six-sided prism terminated by the basal plane. The unsymmetrical etched figures produced artificially on the prism faces indicate, however, that the crystals are hemimorphic and tetartohedral, the only element of symmetry being a polar hexad axis. It is found in compact, granular aggregates, and can be white, yellow, gray, green, or even reddish (in the
eleolite variety). The
hardness is 5.5 - 6, and the
specific gravity 2.56 - 2.66. It is often translucent with a greasy
luster.
The low index of refraction and the feeble double refraction in nepheline are nearly the same as in
quartz; but since in nepheline the sign of the double refraction is negative, while in quartz it is positive, the two minerals are readily distinguished under the
microscope. An important determinative character of nepheline is the ease with which it is decomposed by
hydrochloric acid, with separation of gelatinous silica (which may be readily stained by coloring matters) and cubes of
salt. For this reason, a clear crystal of nepheline becomes cloudy when immersed in
acid.
Although sodium and
potassium are always present in naturally occurring nepheline in approximately the atomic ratio (3:1), artificially prepared crystals have the composition NaAlSiO
4; the corresponding potassium compound, KAISiO
4, which is the mineral kaliophilite, has also been prepared artificially. It has therefore been suggested that the orthosilicate formula, (Na,K)AlSiO
4, represents the true composition of nepheline.
The mineral is one especially liable to alteration, and in the laboratory various substitution products of nepheline have been prepared. In nature it is frequently altered to
zeolites (especially natrolite), sodalite,
kaolin, or compact
muscovite. Gieseckite and liebenerite are pseudomorphs.
Two varieties of nepheline are distinguished, differing in their external appearance and in their mode of occurrence, being analogous in these respects to
sanidine or glassy
orthoclase and common orthoclase respectively. Glassy nepheline has the form of small, colorless, transparent crystals and grains with a vitreous luster. It is characteristic of the later volcanic rocks rich in alkalis, such as
phonolite, nepheline-basalt, leucitebasalt, etc., and also of certain
dike-rocks, such as tinguaite. The best crystals are those which occur with
mica, sanidine,
garnet, etc., in the crystal-lined cavities of the ejected blocks of Monte Somma,
Vesuvius. The other variety, known as elaeolite, occurs as large, rough crystals, or more often as irregular masses, which have a greasy luster and are opaque, or at most translucent, with a reddish, greenish, brownish or grey color. It forms an essential constituent of certain alkaline
plutonic rocks of the
nepheline syenite series, which are typically developed in southern
Norway.
The color and greasy luster of elaeolite (a name given by M. H. Klaproth 1809, from
Greek words for oil and stone;
German ''Fettstein'') are due to the presence of numerous microscopic enclosures of other minerals, possibly
augite or
hornblende. These enclosures sometimes give rise to a chatoyant effect like that of cats-eye and cymophane; and elaeolite when of a good green or red color and showing a distinct band of light is sometimes cut as a gem-stone with a convex surface.
References
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