In chemistry, 'methylene' is a divalent
functional group CH
2 derived formally from
methane. The name "methylene" is used for the following:
★ -CH
2- group (bound by two single
bonds) present e.g. in
dichloromethane (alternative name is methylene chloride);
★ =CH
2 group (bound by one double
bond), present e.g. in
formaldehyde (can be named methylene oxide, but it is not used/recommended). The better example is
methylenecyclopropene.
★ :CH
2 is a
carbene known as methylene, carbenes are highly reactive
organic molecules with a
divalent carbon atom with only six
valence electrons.
Increasing the number of methylene groups in a chain or ring increases the size and the lipid nature (
lipophilicity) of the compound.
See also
★
methyl
★
methylidyne