'Mass transfer' is the phrase commonly used in engineering for physical processes that involve
molecular and
convective transport of
atoms and
molecules within
physical systems. Mass transfer includes both
fluid flow and separation
unit operations.
Some common examples of mass transfer processes are the
evaporation of
water from a pond to the
atmosphere; the
diffusion of
chemical impurities in lakes,
rivers, and
oceans from natural or artificial
point sources; mass transfer is also responsible for the separation of components in an apparatus such as a
distillation column. In
heating, ventilating, and air-conditioning (HVAC), examples of a heat and mass exchangers are
cooling towers and
evaporative coolers where evaporation of water cools that portion which remains as a liquid, as well as cooling and humidifying the
air passing through.
The driving force for mass transfer is a difference in concentration; the random motion of molecules causes a net transfer of mass from an area of high concentration to an area of low concentration. The amount of mass transfer can be quantified through the calculation and application of
mass transfer coefficients. Mass transfer finds extensive application in
chemical engineering problems, where material balance on components is performed.
In
astronomy, mass transfer is the process by
which
matter gravitationally bound to a body, usually a
star, fills its
Roche lobe and becomes gravitationally bound to a second body, usually a compact object (
white dwarf,
neutron star or
black hole), and is eventually accreted onto it. It is a common phenomenon in
binary systems, and may play an important role in some types of
supernovae, and
pulsars.
Analogies between heat, mass, and momentum transfer
It is important to note that in molecular transport, heat, or mass there are many similarities. The molecular diffusion equations of Newton for momentum,
Fourier for heat, and
Fick for mass are very similar. Therefore many analogies among these three molecular transport process. A great deal of effort has been devoted in the literature to developing analogies among these three transport processes for
turbulent transfer so as to allow prediction of one from any of the others.
Reynolds analogy assumes that the turbulent diffusivities are all equal and that the molecular diffusivities mu/ro and Dab are negligible compared to the turbulent diffusivities. When liquids are present and/or drag is present the analogy is not valid. Other analogies, such as
Von Karman's and
Prandtl's, usually results in poor relations. The most successful and most widely used analogy is the
Chilton and Colburn J-factor analogy. This analogy is based on experimental data for gases and liquids in both the
laminar and turbulent regions. Although it is based on experimental data, it can be shown to satisfy the exact solution derived from laminar flow over a flat plate.
See also
★
Heat transfer
★
Heat exchangers