
'Irving Langmuir' at home (c. 1900).
'Irving Langmuir' (
January 31,
1881 in
Brooklyn, New York -
August 16,
1957 in
Woods Hole, Massachusetts) was an
American chemist and
physicist. His most noted publication was the famous 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on
Gilbert N. Lewis's
cubical atom theory and
Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure".
[1] While at
G.E., from 1909-1950, Langmuir advanced several basic fields of
physics and
chemistry, invented the gas-filled
incandescent lamp, the hydrogen welding technique, and was awarded the 1932
Nobel Prize for Chemistry for his work in
surface chemistry. He was the first industrial chemist to become a Nobel laureate. The
Langmuir Laboratory for Atmospheric Research near
Socorro, New Mexico was named in his honor as was the
American Chemical Society journal for Surface Science, called
Langmuir.
Life
Irving Langmuir was born in
Brooklyn,
New York on January 31, 1881. He was the third child of four of Charles Langmuir and Sadie, née Comings. During his childhood, Langmuir's parents encouraged him to carefully observe nature and to keep a detailed record of his various observations. When Irving was eleven, it was discovered that he had poor eyesight. When this problem was corrected, details that had previously eluded him were revealed. Because of this, his interest in nature and the various complications of nature was heightened.
During his childhood, Langmuir was greatly influenced by his older brother, Arthur Langmuir. Arthur was a research chemist who encouraged Irving to be curious about nature and how things work. Arthur helped Irving set up his first chemistry lab in the corner of his bedroom, and he was content to answer the myriad of questions that Irving would pose. Langmuir's hobbies included mountaineering, skiing, piloting his own plane, and classical music. In addition to his professional interest in the politics of atomic energy, he was deeply concerned about wilderness conservation.
Education
He attended his early education at various schools and institutes in America and Paris (1892-1895).
He graduated with a B.S. in
metallurgical engineering from the
Columbia University School of Mines in 1903. He earned his Ph.D. degree in 1906 under Nobel laureate
Walther Nernst in
Göttingen, for research done using the "
Nernst glower", an electric lamp invented by Nerst. His doctoral thesis was entitled “On the Partial Recombination of Dissolved Gases During Cooling.” He later did postgraduate work in chemistry. Langmuir then taught at
Stevens Institute of Technology in
Hoboken, New Jersey, until 1909, when he began working at the
General Electric research laboratory (
Schenectady, New York). In 1912, he married Marion Mersereau.
Scientific work
His initial contributions to science came from his study of light bulbs (a continuation of his Ph.D. work). His first major development was the invention of the
diffusion pump, which ultimately led to the invention of the high-
vacuum tube. A year later, he and colleague
Lewi Tonks discovered that the lifetime of a
tungsten filament was greatly lengthened by filling the bulb with an
inert gas, such as
argon. He also discovered that twisting the filament into a tight coil improved its efficiency. These were important developments in the history of the
incandescent light bulb.

Irving Langmuir - chemist and physicist
As he continued to study filaments in vacuum and different gas environments, he began to study the emission of charged particles from hot filaments (
thermionic emission). He was one of the first scientists to work with
plasmas and was the first to call these ionized gases by that name, because they reminded him of
blood plasma.
[2]
He introduced the concept of
electron temperature and in 1924 invented the diagnostic method for measuring both temperature and
density with an electrostatic probe, now called a
Langmuir probe and commonly used in plasma physics. The current of a biased probe tip is measured as a function of bias voltage to determine the local plasma temperature and density. He also discovered atomic
hydrogen, which he put to use by inventing the atomic hydrogen welding process; the first plasma weld ever made. Plasma welding has since been developed into
gas tungsten arc welding.
Later years
Following
World War I Langmuir contributed to atomic theory and the understanding of atomic structure by defining the modern concept of
valence shells and
isotopes.
He joined
Katharine B. Blodgett to study thin films and surface absorption. They introduced the concept of a
monolayer (a layer of material one molecule thick) and the two-dimensional physics which describe such a surface. In 1932 he received the
Nobel Prize for Chemistry "for his discoveries and investigations in
surface chemistry."
In 1938, Langmuir's scientific interests began to turn to
atmospheric science and
meteorology. One of his first ventures, although tangentially related, was a refutation the claim of entomologist Charles H. T. Townsend that the
deer botfly flew at speeds in excess of 800 miles per hour. Langmuir estimated the fly's true speed at 25 miles per hour.
During
World War II, Langmuir worked on improving naval
sonar for submarine detection, and later to develop protective smoke screens and methods for
deicing aircraft wings. This research led him to theorize that the introduction of
dry ice and
iodide into a sufficiently moist cloud of low temperature could induce precipitation (
cloud seeding); though in frequent practice, particularly in
Australia and the
People's Republic of China, the efficacy of this technique remains controversial today.
In 1953 Langmuir coined the term "
pathological science", describing research conducted with accordance to the
scientific method, but tainted by unconscious bias or subjective effects. This is in contrast to
pseudoscience, which has no pretense of following the scientific method. In his original speech, he presented
ESP and
flying saucers as examples of pathological science; since then, the label has been applied to
polywater and
cold fusion.
After a short illness, he died of a heart attack in 1957. His obituary ran on the front page of the
New York Times.
References
1. Langmuir, I. (1919). "The Arrangement of Electrons in Atoms and Molecules", ''Journal of the American Chemical Society''. Vol. 41, No. 6, 861.
2. What is Plasma? - Coalition for Plasma Science
Patents
★ Langmuir, , "''Incandescent Electric Lamp''"
★ Langmuir, , "''Electron-discharge apparatus and method of operating the same''"
★ Langmuir, , "''Method of and apparatus for controlling x-ray tubes''"
External links
★
Langmuir Journal ACS Chemistry Journal of Surfaces and Colloids
★ "''
Langmuir, Irving''" Infoplease.com.
★ "''
Irving Langmuir's Ball Lightning Tube''". Ball Lightning Page.
Science Hobbyist.
★ "''
Irving Langmuir shows Whitney one of his inventions, the Pliotron tube. ca. 1920.''".
Willis Rodney whitney: the "Father of basic research in industry".
★
"Pathological Science" - noted lecture of 18 December 1953 at GE Labs