'Ferdinand Frederick Henri Moissan' (
September 28,
1852 –
February 20,
1907) was a
French chemist who won the 1906
Nobel Prize in Chemistry for his work in isolating
fluorine from its compounds.
Preparation of Fluorine
Fluorine's existence had been well known for many years, but all attempts to prepare it had failed - and some experimenters had died in the attempt.
Moissan eventually succeeded in preparation by
electrolysing a
solution of
potassium hydrogen fluoride (KHF
2) in liquid
hydrogen fluoride (HF). The mixture was needed because hydrogen fluoride is a non-conductor. The device was built with
platinum/
iridium electrodes in a platinum holder and cooled the apparatus to -50
°C. The result was to completely isolate the hydrogen produced from the negative
electrode from the fluorine produced at the positive one.
[1][2] This is essentially still the way fluorine is produced today.
Further studies
Moissan went on to study fluorine chemistry in great detail, contributed to the development of the
electric arc furnace and attempted to use pressure to synthesize
diamonds from the more common form of
carbon. In 1893, Moissan began studying fragments of a meteorite found in
Meteor Crater near
Diablo Canyon in
Arizona. In these fragments he discovered minute quantities of a new mineral and, after extensive research, Moissan concluded that this mineral was made of silicon carbide. In 1905, this mineral was named
Moissanite, in his honor.
Death
He died suddenly in
Paris in February 1907, shortly after his return from receiving the Nobel Prize in
Stockholm. His death was attributed to an accute
appendicitis. It is not known whether his experiments with fluorine contributed to his early death.
See also
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Chemistry
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Pharmacy
References
1. Action d'un courant électrique sur l'acide fluorhydrique anhydre, H. Moissan, , , Comptes rendus hebdomadaires des séances de l'Académie des sciences, 1886
2. Sur la décomposition de l'acide fluorhydrique par un courant électrique, H. Moissan, , , Comptes rendus hebdomadaires des séances de l'Académie des sciences, 1886
★
Henri Moissan (To 150th Anniversary of His Birthday), A.G. Morachevskii, , , Journal Russian Journal of Applied Chemistry, 2002
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Frederic Henri Moissan, on the 120th anniversary of his birth, G. V. Samsonov, V. A. Obolonchik, , , Journal Powder Metallurgy and Metal Ceramics, 1886
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The scientific contributions of Moissan, Flahaut J., , , Ann Pharm Fr., 1999
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La Vie et les travaux de Henri Moissan written by Paul Lebau in 1931
External links
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Biography Biography from Nobelprize.org website
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Scientific genealogy
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Biography