'Electrochromism' is the phenomenon displayed by some chemical species of reversibly changing color when a burst of
charge is applied.
One good example of an electrochromic material is
polyaniline which can be formed either by the
electrochemical or chemical
oxidation of
aniline. If an
electrode is immersed in
hydrochloric acid which contains a small concentration of aniline, then a film of polyaniline can be grown on the electrode. Depending on the redox state, polyaniline can either be pale yellow or dark green/black. Other electrochromic materials that have found technological application include the
viologens and
polyoxotungstates. Other electrochromic materials include
tungsten oxide (WO
3), which is the main chemical used in the production of electrochromic windows or
smart windows.
As the color change is persistent and energy need only be applied to effect a change, electrochromic materials are used to control the amount of
light and
heat allowed to pass through
windows ("
smart windows"), and has also been applied in the
automobile industry to automatically
tint rear-view mirrors in various
lighting conditions.
Viologen is used in conjunction with
titanium dioxide (TiO
2) in the creation of small digital displays. It is hoped that these will replace
LCDs as the viologen (which is typically dark blue) has a high contrast to the bright color of the titanium white, therefore providing a high visibility of the display.