
Diopside
'Diopside' is a
monoclinic pyroxene mineral with composition MgCaSi
2O
6. It forms complete solid solution series with
hedenbergite (FeCaSi
2O
6) and
augite, and partial solid solutions with
orthopyroxene and
pigeonite. It forms variably colored, but typically dull green crystals in the
monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a
Mohs hardness of six and a
specific gravity of 3.25 to 3.55. It is transparent to translucent with
indices of refraction of n
α=1.663–1.699, n
β=1.671–1.705, and n
γ=1.693–1.728. The optic angle is 58° to 63°.
Diopside is found in
ultramafic (
kimberlite and
peridotite)
igneous rocks, and diopside-rich augite is common in
mafic rocks, such as olivine
basalt and
andesite. Diopside is also found in a variety of
metamorphic rocks, such as in contact metamorphosed
skarns developed from high silica
dolomites. It is an important mineral in the
Earth's
mantle and is common in
peridotite xenoliths erupted in
kimberlite and alkali
basalt.
At relatively high temperatures, there is a miscibility gap between diopside and
pigeonite, and at lower temperatures, between diopside and
orthopyroxene. The
calcium/(calcium+
magnesium+
iron) ratio in diopside that formed with one of these other two pyroxenes is particularly sensitive to temperature above 900°C, and compositions of diopside in peridotite xenoliths have been important in reconstructions of temperatures in the
Earth's mantle.
Gemstone quality diopside is found in two forms: the black star diopside and the chrome diopside (which includes
chromium giving it a rich green colour). At 5.5–6.5 on the Mohs scale, chrome diopside is relatively soft to scratch. Mohs scale of hardness does not measure tensile strength or resistance to fracture.
Chrome diopside ((Ca,Na,Mg,Fe,Cr)
2(Si,Al)
2O
6) is a common constituent of
peridotite xenoliths, and dispersed grains are found near
kimberlite pipes, and as such are a prospecting indicator for
diamonds. Occurrences are reported in Canada, South Africa, Russia and a wide variety of other locations.
Diopside was first described about 1800 and derives its name from the Greek ''dis'', "twise", and ''òpsè'', "face" in reference to the two ways of orienting the vertical prism.
References
★ Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., Wiley, pp 403-404, ISBN 0-471-80580-7
★
Mindat: Diopside
★
Mindat: Chromian diopside, with locales
★
Webmineral
★
Mineral galleries
★ ''Handbook of Mineralogy'', Mineral Data Publishing, 2001,
Diopside PDF version
★ http://gemstone.org/gem-by-gem/english/diopside.html
★
Greek-English-Greek dictionary