DIFFUSION


:''This article is about the physical mechanism of diffusion. For alternative meanings, see'' diffusion (disambiguation).
Schematic drawing of the effects of diffusion through a cell membrane.

'Diffusion' is the phenomenon of random motion causing a system to decay towards uniform conditions. For example, diffusion of particles causes a net movement of particles from areas of higher concentration to areas of lower concentration until equilibrium is reached. This is simply the statistical outcome of random motion: diffusion is a ''spontaneous'' process (more familiarly known as a "passive" form of transport, rather than "active"). Diffusion can affect a variety of different quantities. Examples include diffusion of concentration, heat, or momentum. Diffusion increases entropy, decreasing Gibbs free energy, and therefore is thermodynamically favorable.
Diffusion can be described mathematically by the diffusion equation. This equation is derived from Fick's law, which states that the net movement of diffusing substance per unit area of section (the flux) is proportional to the concentration gradient (how steeply the concentration changes in space), and is toward lower concentration. (Thus if the concentration is uniform there will be no net motion.) The constant of proportionality is the diffusion coefficient, which depends on the diffusing species and the material through which diffusion occurs. Fick's law is an assumption that may not hold for a given diffusive system (e.g., the diffusion may depend on concentration in addition to concentration gradient), in which case the motion would not be described by the normal (simple, Fickian) diffusion equation. An analogous statement of Fick's law, for heat instead of concentration, is Fourier's law.
Diffusion can also be described using discrete quantities (the diffusion equation has derivatives and thus applies to continuous quantities). A common model of discrete diffusion is the random walk. A random walk model is connected to the diffusion equation by considering an infinite number of random walkers starting from a non-uniform configuration, where the evolution of the concentration is described by the diffusion equation.
The spreading of any quantity that can be described by the diffusion equation or a random walk model (e.g. momentum, ideas, price) can be called diffusion.
Diffusion is often important in systems experiencing an applied force. In a conducting material, the net motion of electrons in an electrical field quickly reaches a terminal velocity (resulting in a steady current described by Ohm's law) because of the thermal (diffusive) motions of atoms. The Einstein relation relates the diffusion coefficient to the mobility of particles.
In cell biology, diffusion is a main form of transport within cells and across cell membranes.

Contents
Types of diffusion
Diffusion displacement
Isotope separation
Diffusion across biological membranes
References
See also
External links

Types of diffusion


Diffusion is the movement of particles from an area where their concentration is high to an area that always has low concentration.
Diffusion includes not only diffusion of particles, but transport phenomena occurring within thermodynamic systems under the influence of thermal fluctuations (i.e. under the influence of disorder; this excludes transport through a hydrodynamic flow, which is a macroscopic, ordered phenomenon), basically making both sides of the lipid bilayer of the same saturation of chemicals.
Diffusion is the process through which 'velocity thermodynamic system' at local thermodynamic equilibrium returns to global thermodynamic equilibriums, through the homogenization of the values of its intensive parameters.

Atomic diffusion

Light diffusion

Brownian motion, for example of a single particle in a solvent

Collective diffusion, the diffusion of a large number of (possibly interacting) particles

Effusion of a gas through small holes.

Electron diffusion, resulting in electric current

Heat flow (thermal diffusion)

Itō diffusion

Knudsen diffusion

Momentum diffusion, ex. the diffusion of the hydrodynamic velocity field

Osmosis

Photon diffusion

Reverse diffusion

Self-diffusion

Diffusion displacement


The diffusion displacement can be described by the following formula
:langle r_{k}^2
angle=2cdot kcdot Dcdot t
where , k is the dimensions of the system and can be one, two or three. , D is the diffusion coefficient of the particles and , t is time. For the three-dimensional systems the above equation will be:
:langle x^2
angle + langle y^2
angle + langle z^2
angle = langle r_{3}^2
angle = 6cdot Dcdot t

Isotope separation



Gaseous diffusion

Liquid thermal diffusion
Diffusion across biological membranes


Facilitated diffusion

★ Ion diffusion through ion channels

★ Simple diffusion, not requiring a special protein channel

★ Diffusion in the respiratory system - in the alveoli of mammalian lungs, due to differences in partial pressures across the alveolar-capillary membrane, oxygen diffuses into the blood and carbon dioxide diffuses out
such as dye in water it diffuses out to change the colour of water in a matter of seconds.
'An Experiment to Demonstrate Diffusion'''
''Requirements:''
1 wide glass tube
2 Corks
Cotton wool soaked in ammonia solution
4 square sized red litmus paper
''Procedure:'' Cork the two ends of the wide glass tube. Plug the wet cotton wool with one of the corks and hang the litmus papers with a thread within the tube.
''Observation:'' The red litmus papers turn blue.
''Interpretation:'' The ammonia molecules by diffusion travels from higher concentration which is the cotton wool to lower concentration which is the rest of the glass tube.As the ammonia solution is alkaline, the red litmus papers turn blue. By changing the concentration of ammonia , the rate of color change of the litmus papers can be changed.

References


See also



Bohm diffusion

Brownian motion

Collective diffusion

Diffusion equation

Diffusion equilibrium

Diffusion MRI

Fick's law of diffusion

Isotope separation

Mass transfer

Osmosis

Transport phenomena

Local time (mathematics)

External links





Some pictures that display diffusion and osmosis

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