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'Carbonate rocks' are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone and dolomite, composed of calcite (CaCO₃) and the mineral dolomite (CaMg(CO₃)₂) respectively. Chalk and tufa are also minor sedimentary carbonates.
Calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature, pH, and dissolved ion concentrations. Calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases.
When conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together or it can fill fractures.
Karst topography and caves develop in carbonate rocks due to their solubility in dilute acidic groundwater. Cooling groundwater or mixing of different groundwaters will also create conditions suitable for cave formation.
Marble is the metamorphic carbonate rock. Rare igneous carbonate rocks exist as intrusive carbonatites and even more rare volcanic carbonate lava.