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In solid state physics and related applied fields, the 'band gap', also called an 'energy gap' or 'stop band', is a region where a particle or quasiparticle is forbidden from propagating. For insulators and semiconductors, the band gap generally refers to the energy difference between the top of the valence band and the bottom of the conduction band.

Contents

In semiconductor physics

Mathematical interpretation

List of band gaps

In photonics and phononics

References

See also

Chemicals

In semiconductor physics

In semiconductors and insulators, electrons are confined to a number of bands of energy, and forbidden from other regions. The term "band gap" refers to the energy difference between the top of the valence band and the bottom of the conduction band, where electrons are able to jump from one band to another.
The conductivity of intrinsic semiconductors is strongly dependent on the band gap. The only available carriers for conduction are the electrons which have enough thermal energy to be excited across the band gap.
Band gap engineering is the process of controlling or altering the band gap of a material by controlling the composition of certain semiconductor alloys, such as GaAlAs, InGaAs, and InAlAs. It is also possible to construct layered materials with alternating compositions by techniques like molecular beam epitaxy. These methods are exploited in the design of heterojunction bipolar transistors (HBTs), laser diodes and solar cells.
The distinction between semiconductors and insulators is a matter of convention. One approach is to consider semiconductors a type of insulator with a low band gap. Insulators with a higher band gap, usually greater than 3 eV, are not considered semiconductors and generally do not exhibit semiconductive behaviour under practical conditions. Electron mobility also plays a role in determining a material's informal classification.
Band gaps depend on temperature because of thermal expansion. Band gaps also depend on pressure. Band gaps can be either direct or indirect bandgaps, depending on the band structure.

Mathematical interpretation

Classically, the ratio of probabilities that two states with an energy difference ''ΔE'' will be occupied by an electron is given by the Boltzmann factor:
:
ight)}
where:
:e is the exponential function
:$,\; Delta\; E$ is the energy difference
:$,\; k$ is Boltzmann's constant
:$,\; T$ is temperature
At the Fermi level (or chemical potential), the probability of a state being occupied is ½. If the Fermi level is in the middle of a band gap of 1 eV, this ratio is ''e'' ^-20 or about 0.5•10^-9 at the room-temperature thermal energy of 25 meV.

List of band gaps

Material	Symbol	Band gap (eV) @ 300K
Silicon	Si	1.11 [1]
Germanium	Ge	0.67 1
Silicon carbide	SiC	2.86 1
Aluminum phosphide	AlP	2.45 1
Aluminum arsenide	AlAs	2.16 1
Aluminium antimonide	AlSb	1.6 1
Gallium(III) phosphide	GaP	2.26 1
Gallium(III) arsenide	GaAs	1.43 1
Gallium(III) nitride	GaN	3.4 1
Gallium(II) sulphide	GaS	2.5 (@ 295 K)
Gallium antimonide	GaSb	0.7 1
Indium(III) phosphide	InP	1.35 1
Indium(III) arsenide	InAs	0.36 1
Zinc sulfide	ZnS	3.6 1
Zinc selenide	ZnSe	2.7 1
Zinc telluride	ZnTe	2.25 1
Cadmium sulfide	CdS	2.42 1
Cadmium selenide	CdSe	1.73 1
Cadmium telluride	CdTe	1.58 1
Lead(II) sulfide	PbS	0.37 1
Lead(II) selenide	PbSe	0.27 1
Lead(II) telluride	PbTe	0.29 1

In photonics and phononics

In photonics band gaps or stop bands are ranges of photon frequencies where, if tunneling effects are neglected, no photons can be transmitted through a material. A material exhibiting this behaviour is known as a photonic crystal.
Similar physics applies to phonons in a phononic crystal.

References

1. Solid State electronic Devices, , Ben G., Streetman, Prentice Hall, 2000,

See also

Chemicals

★ Aluminium gallium arsenide

★ Boron nitride

★ Indium gallium arsenide

★ Gallium arsenide

★ Germanium

★ Metallic hydrogen
===List of electronics topics===

★ Electronics

★ Bandgap voltage reference

★ Condensed matter physics

★ Direct bandgap

★ Electrical conduction

★ Electron hole

★ Field effect transistor

★ Indirect bandgap

★ Photodiode

★ Photoresistor

★ Photovoltaics

★ Solar cell

★ Solid state physics

★ Semiconductor

★ Semiconductor devices

★ Strongly correlated material

★ Valence band