
Alunite.
'Alunite', or alumstone, is a
mineral that was first observed in the
15th century in
Monti della Tolfa, north to
Rome, where it was mined for the manufacture of
alum. First called ''aluminilite'' by
J.C. Delametherie in 1707, this name was contracted by
François Beudant in 1824 to alunite.
Distinct
crystals of alunite are rarely found in cavities in the massive material. Alunite crystallizes in the
hexagonal system with crystals forming
trigonal pyramids that resemble rhombohedra with interfacial angles of 90 50', so that they resemble cubes in appearance. Minute glistening crystals have also been found loose in cavities in altered
rhyolite. Alunite varies in color from white to yellow gray. The
hardness is 4 and the
specific gravity is between 2.6 and 2.8. The mineral is a hydrated
aluminium potassium sulfate, KAl
3(SO
4)
2(OH)
6. Sodium substitutes for potassium and when high in sodium it is called natroalunite. It is insoluble in water or weak acids, but soluble in
sulfuric acid.
Jarosite is an iron analogue in which Fe
3+ replaces the aluminium. It occurs as a secondary mineral on iron sulfate ores.
Alunite occurs as veins and replacement masses in
trachyte,
rhyolite, and similar potassium rich
volcanic rocks It is formed by the action of
sulfuric acid bearing solutions on these rocks during the
oxidation and leaching of metal sulfide deposits. Alunite also is found near volcanic
fumaroles. The white, finely granular masses closely resemble finely granular
limestone,
dolomite,
anhydrite, and
magnesite in appearance. The more compact kinds from Hungary are so hard and tough that they have been used for millstones.
Historically extensive deposits were mined in
Tuscany and
Hungary, and at
Bulahdelah. Currently found at Tolfa,
Italy. In the United States it is found in the San Juan district of
Colorado;
Goldfield, Nevada;
Marysvale, Utah; and Red Mountain in
Patagonia, Arizona. The Arizona occurrence lies appropriately above a canyon named ''Alum Gulch''. Alunite is mined as an ore of both potassium and aluminium at Marysvale. Some of the
ore deposits were located by airborne and satellite
multispectral imaging.
References
★
Dana's Manual of Mineralogy, , Cornelius S., Hurlbut, , 1966, ISBN 0-471-03288-3
★
Manual of Mineralogy, , Cornelius S., Hurlbut, , 1985, ISBN 0-471-80580-7
External links
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Mineral Galleries
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Webmineral
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